Wheel Chair Batteries

Just as everyone is running around and saying that the memory effect is a myth, here I am, saying that it is true. OK, so, why is this? First of all, the term memory effect is quite unscientific. People tend to attribute any failure of a NiCd to memory.
Let us define memory as the phenomenon where the discharge voltage for a given load is lower than it should be. This can give the appearance of a lowered capacity, while in reality, it is more accurate to term it voltage depression.
Memory is also hard to reproduce, which makes it hard to study. Originally, memory effect was seen in spacecraft batteries subjected to a repeated discharge/charge cycle that was a fixed percentage of total capacity (due to the earth's shadow). After many cycles, when called upon to provide the full capacity, the battery failed to do so. Since we aren't in space, the above is not really relevant...
Let us look at various causes of "memory" or voltage depression.
Memory can be attributed to changes in the negative or cadmium plate. Recall that charging involves converting

Cd(0H) to Cd metal.
2
Ordinarily, and under moderate charging currents, the cadmium that is deposited is microcrystalline (i.e. very small crystals). Now, metallurgical thermodynamics states that grain boundaries (boundaries between the crystals) are high energy regions, and given time, the tendency of metals is for the grains to coalesce and form larger crystals. This is bad for the battery since it makes the cadmium harder to dissolve during high current discharge, and leads to high internal resistance and voltage depression. The trick to avoiding memory is avoiding forming large crystal cadmium. Very slow charging is bad, as slow growth aids large crystal growth (recall growing rock candy). High temperatures are bad, since the nucleation and growth of crystals is exponentially driven by temperature. The problem is that given time, one will get growth of cadmium crystals, and thus, one needs to reform the material. Partial cycling of the cells means that the material deep with the plate never gets reformed. This leads to a growth of the crystals. By a proper execution of a discharge/charge cycle, one destroys the large crystal cadmium and replace it with a microcrystalline form best for discharge.
This does NOT mean that one needs to cycle one's battery each time it is used. This does more harm than good, and unless it is done on a per cell basis, one risks reversing the cells and that really kills them. Perhaps once in a while, use the pack until it is 90% discharged, or to a cell voltage of 1.0V under light load. Here, about 95% of the cells capacity is used, and for all intensive purposes, is discharged. At this point, recharge it properly, and that's it.
The more common "memory effect" isn't memory at all, but voltage depression caused by overcharging. Positive plate electrochemistry is very complicated, but overcharging changes the crystal structure of the nickelic hydroxide from beta-Nickelic Hydroxide to gamma-Nickelic hydroxide. The electrochemical potential of the gamma form is about 40 to 50 mV less than the beta form. This results in a lower discharge voltage. In a six cell (7.2v) pack, this means a loss of 300 mV. Trick? Don't overcharge. Leaving cells on a trickle charger encourages formation of gamma nickelic hydroxide. Expect the cells to discharge at a lower voltage.

NiMH (Nickel Metal Hydride) Battery Storage
Duracell NiMH Battery Storage

Ni-MH batteries can give years of safe and reliable service if they are used in accordance with recommended procedures and are not abused. Batteries should be kept clean and dry both during use and storage. They can be stored for many months in a charged or discharged state without any detrimental effects as long as they are not exposed to extreme temperatures for any long period of time. After periods during which the battery has not been used, the battery should be charged before being placed in service. Extended overcharging or overheating of the battery should always be avoided.

Varta NiMH: Battery storage in any state of charge is possible. Storage temperatures between -20 and +35 are recommended, relative humidity approximately 50%. In case of long term storage cells must be recharged once a year.


Sanyo NiMH: Under the recommended storage conditions (-20 C to +35 C) the Twicel can be stored indefinitely in either a charged or uncharged state. Recovery may take several cycles. If a battery is stored for a prolonged time connected to a load, electrolyte fluid will leak, the battery will begin to deteriorate, and capacity will be impaired after storage. During long time storage battery deactivation may tend to occur, and for this reason charging may stop early during recharging after storage. This problem can be solved by charging and discharging the battery several times.
Sanyo NiMh Battery Storage: Generally speaking, a loss of voltage and capacity of batteries due to self-discharge during storage is unavoidable. The factors inducing this self-discharge of Nickel-Metal Hydride batteries is listed below:

1. The inside of the cell is a hydrogen atmosphere at low pressure, which gradually reduces the active materials at the positive electrode, resulting in a drop of cell capacity. Accompanied by this, the negative electrode which is thermodynamically unstable in its charged state gradually gives off hydrogen gas, thus reducing cell capacity.
2. The active materials at the positive electrode in its charged state self-decompose, causing the cell capacity to decrease.
3. Impurities within the cell, especially nitric ions, are reduced at the negative electrode and diffuse to the positive electrode where they are oxidized. This results in a lowered cell capacity.

The factors (2) and (3) also apply to Nickel-Cadmium Batteries. As discussed above, the self-discharge of Nickel-Metal-Hydride Batteries during battery storage causes a loss in stored energy. However, once recharged, this lost portion of the capacity will be almost completely restored. The self-discharge characteristics of Nickel Metal Hydride batteries is affected by storage temperature. . . If the battery is stored at high temperatures, the self-discharge will be accelerated. Also, the longer the storage period, the more the cell capacity decreases. As mentioned above, since the capacity of Nickel Metal Hydride batteries lost by self-discharge can be restored by recharging, there are virtually no noticeable adverse effects of battery storage. However, prolonged storage at high temperatures may deteriorate or deform the gasket or the separator, and should be avoided. Either fully charged or discharged, Nickel Metal Hydride ( NiMH ) batteries may be stored indefinitely. . . In either cased (charged or discharged) the capacity is recovered within two or three charge / discharge cycles.

Panasonic NiMH Battery Storage

Because long term storage can accelerate battery self-discharge, and lead to the deactivation of reactants, locations where the temperature ranges between +10°C and +30°C are suitable for long term storage.

When charging for the first time after long term storage, the deactivation of reactants may lead to increased battery voltage, and decreased battery capacity. Restore such batteries to orginal performance by repeating several cycles of charging and discharging.

When storing batteries for more than one year, charge at least once a year to prevent leakage and deterioration of performance due to self-discharging.